[Journal logo]

Volume 67 
Part 10 
Pages m1464-m1465  
October 2011  

Received 23 September 2011
Accepted 25 September 2011
Online 30 September 2011

[xu5330sup1]
[3d view]

[Cited in]
[Download citation]
Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.003 Å
R = 0.039
wR = 0.113
Data-to-parameter ratio = 16.2
Details
Open access

Bis([mu]-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate

Wei-Wei Li,a Yue Bing,a Mei-Qin Zha,a Tian-Hua Lia and Xing Lia*

aFaculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China
Correspondence e-mail: lix905@126.com, lixing@nbu.edu.cn

In the centrosymmetric dinuclear title complex, [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxylate anions. A pair of 2-phenylquinoline-4-carboxylate anions bridge two Mn cations, forming the dinuclear molecule. An intramoleculr O-H...O hydrogen bond occurs. Intermolecular O-H...O and O-H...N hydrogen bonds are present in the crystal structure.

Related literature

For applications of coordination polymers, see: Wang et al. (2009[Wang, M., Xie, M. H., Wu, C. D. & Wang, Y. G. (2009). Chem. Commun. 17, 2396-2398.]); Xi et al. (2009[Xi, P.-X., Xu, Z.-H., Chen, F.-J., Zeng, Z.-Z. & Zhang, X.-W. (2009). J. Inorg. Biochem. 103, 210-218.]); Xu et al. (2008[Xu, Z.-H., Chen, F.-J., Xi, P.-X., Liu, X.-H. & Zeng, Z.-Z. (2008). J. Photochem. Photobiol. A, 196, 77-83.]); Ferey (2008[Ferey, G. (2008). Chem. Soc. Rev. 37, 191-214.]). For a related structure, see: Shen et al. (2007[Shen, Y.-C., Li, Z.-J., Cheng, J.-K., Qin, Y.-Y. & Yao, Y.-G. (2007). Inorg. Chem. Commun. 10, 888-890.]).

[Scheme 1]

Experimental

Crystal data

  • [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O

  • Mr = 1535.35

  • Monoclinic, P 21 /c

  • a = 14.926 (4) Å

  • b = 13.847 (4) Å

  • c = 17.717 (5) Å

  • [beta] = 96.919 (4)°

  • V = 3635.1 (18) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.42 mm-1

  • T = 296 K

  • 0.35 × 0.15 × 0.12 mm
Data collection

  • Bruker SMART CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.927, Tmax = 0.951

  • 31242 measured reflections

  • 8315 independent reflections

  • 5656 reflections with I > 2[sigma](I)

  • Rint = 0.044
Refinement

  • R[F2 > 2[sigma](F2)] = 0.039

  • wR(F2) = 0.113

  • S = 1.03

  • 8315 reflections

  • 512 parameters

  • 4 restraints

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 0.41 e Å-3

  • [Delta][rho]min = -0.28 e Å-3

Table 1
Selected bond lengths (Å)

Mn1-O1 2.1740 (14)
Mn1-O3 2.1557 (15)
Mn1-O4i 2.1148 (14)
Mn1-O5 2.2358 (16)
Mn1-N3 2.2706 (16)
Mn1-N4 2.2914 (15)
Symmetry code: (i) -x, -y, -z+2.

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O5-H5A...O2 0.85 (2) 1.81 (2) 2.630 (2) 161 (3)
O5-H5B...N2ii 0.83 (2) 2.04 (2) 2.868 (2) 176
O6-H6A...O1iii 0.89 (5) 2.30 (5) 3.175 (3) 167
O6-H6B...N1iv 0.87 (2) 2.23 (2) 3.051 (3) 157
Symmetry codes: (ii) [-x, y+{\script{1\over 2}}, -z+{\script{3\over 2}}]; (iii) [x, -y+{\script{1\over 2}}, z-{\script{1\over 2}}]; (iv) [-x+1, y+{\script{1\over 2}}, -z+{\script{3\over 2}}].

Data collection: SMART (Bruker, 2007[Bruker (2007). SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5330 ).

Acknowledgements

The work was supported by the Ningbo University Foundation (XK1066, XYL08004), the training funds of excellent theses for Masters in Ningbo University (PY20090012, PY20100007), the Youth Talent programs of Zhejiang Province (2010R405017) and the K. C. Wong Magna Fund in Ningbo University, China.

References

Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA.
Ferey, G. (2008). Chem. Soc. Rev. 37, 191-214.  [ISI] [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Shen, Y.-C., Li, Z.-J., Cheng, J.-K., Qin, Y.-Y. & Yao, Y.-G. (2007). Inorg. Chem. Commun. 10, 888-890.  [ISI] [CSD] [CrossRef] [ChemPort]
Wang, M., Xie, M. H., Wu, C. D. & Wang, Y. G. (2009). Chem. Commun. 17, 2396-2398.  [CSD] [CrossRef]
Xi, P.-X., Xu, Z.-H., Chen, F.-J., Zeng, Z.-Z. & Zhang, X.-W. (2009). J. Inorg. Biochem. 103, 210-218.  [ISI] [CSD] [CrossRef] [ChemPort]
Xu, Z.-H., Chen, F.-J., Xi, P.-X., Liu, X.-H. & Zeng, Z.-Z. (2008). J. Photochem. Photobiol. A, 196, 77-83.  [CrossRef] [ChemPort]

Acta Cryst (2011). E67, m1464-m1465   [ doi:10.1107/S1600536811039341 ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.