Acta Cryst. (2011). E67, m1409-m1410  [ doi:10.1107/S1600536811037627 ]

Chloridodiphenyl{[1-(1,3-thiazol-2-yl-N)ethylidene]-4-phenylthiosemicarbazidato-²N¹,S}tin(IV) methanol monosolvate

S. R. Arumugam, S. S. R. Dasary, R. Venkatraman, H. Yu and F. R. Fronczek

Abstract: The title compound, [Sn(C₆H₅)₂(C₁₂H₁₁N₄S₂)Cl]·CH₄O, is formed during the reaction between 2-acetylthiazole 4-phenylthiosemicarbazone (Hacthptsc) and diphenyltin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octahedral geometry with the [N₂S] anionic tridentate thiosemicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn-Cl distance is 2.5929 (6), Sn-S is 2.4896 (6) and Sn-N to the central N is 2.3220 (16) Å. The MeOH molecules link the Sn complexes into one-dimensional chains via N-HO and O-HCl hydrogen bonds.

Online 30 September 2011

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