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Acta Cryst. (2012). E68, m43 [ doi:10.1107/S1600536811050999 ]
-4-azidobenzoato-
2O:O')bis[(N,N-dimethylformamide-
O)copper(II)]Abstract: The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal-organic compound having a paddle-wheel-type structure. The Cu
Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu
Cu bond is also considered.
Online 14 December 2011
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