[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m43  [ doi:10.1107/S1600536811050999 ]

Tetrakis([mu]-4-azidobenzoato-[kappa]2O:O')bis[(N,N-dimethylformamide-[kappa]O)copper(II)]

A. Wang

Abstract: The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal-organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu...Cu bond is also considered.

Online 14 December 2011


Copyright © International Union of Crystallography
IUCr Webmaster