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Acta Cryst. (2012). E68, m88 [ doi:10.1107/S1600536811054596 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-pyridinium-2-carboxylato-![[kappa]](/logos/entities/kappa_rmgif.gif)
2O:O')bis[triaqua(sulfato-O)manganese(II)]Abstract: The asymmetric unit of the title compound, [Mn2(SO4)2(C6H5NO2)2(H2O)6], comprises half of a centrosymmetric dimer. The MnII atom is coordinated by two O atoms of the monodentate carboxylate ligand, an O atom of the sulfate anion in axial position and three water molecules in a distorted octahedral geometry. In the crystal, molecules are connected through N-H
O and O-HO hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by intermolecular ![[pi]](/logos/entities/pi_rmgif.gif)
- interactions [centroid-centroid distance = 3.842 (2) Å].
Online 23 December 2011
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