Acta Cryst. (2012). E68, o185 [ doi:10.1107/S1600536811053992 ]
Abstract: In the title compound, C7H10N+·ClO4-·C12H24O6, the 4-methylanilinium cation interacts with an 18-crown-6 molecule forming a rotator-stator-like structure through bifurcated N-H(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether molecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°.
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