Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 1 (January 2012)

organic compounds

Acta Cryst. (2012). E68, o185    [ doi:10.1107/S1600536811053992 ]

4-Methyl­anilinium perchlorate 18-crown-6 clathrate

Y.-F. Wang

Abstract: In the title compound, C7H10N+·ClO4-·C12H24O6, the 4-methyl­anilinium cation inter­acts with an 18-crown-6 mol­ecule forming a rotator-stator-like structure through bifurcated N-H...(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°.

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