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Acta Cryst. (2012). E68, m11  [ doi:10.1107/S1600536811051476 ]

Bis[2-(1-iminoethyl)phenolato-[kappa]2N,O]nickel(II)

N. Wang

Abstract: There are one and a half independent molecules in the asymmetric unit of the title compound, [Ni(C8H8NO)2], one of which is situated on an inversion center. In both molecules, the NiII ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Intermolecular N-H...O hydrogen bonds link three molecules into centrosymmetric trimer. The crystal packing exhibits weak intermolecular C-H...O hydrogen bonds and voids of 37 Å3.

Online 3 December 2011


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