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Acta Cryst. (2012). E68, m14-m15  [ doi:10.1107/S1600536811051841 ]

trans-Dichloridobis[dicyclohexyl(4-isopropylphenyl)phosphane-[kappa]P]platinum(II) acetone monosolvate

B. Vuba and A. Muller

Abstract: The title compound, [PtCl2(C21H33P)2]·C3H6O, crystallizes with an accompanying acetone solvent molecule. The metal atom shows a distorted square-planar coordination environment, with a P-Pt-P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55 (2):0.45 (2) and 0.58 (2):0.42 (2). The solvent molecule was also disordered over two orientations in a 1:1 ratio. The crystal studied was a non-merohedral twin with a twin component of 32.4%.

Online 7 December 2011


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