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Acta Cryst. (2012). E68, m65-m66  [ doi:10.1107/S1600536811053736 ]

Tris(ethylenediamine-[kappa]2N,N')cobalt(III) aquatris(oxalato-[kappa]2O1,O2)indate(III)

Z. Zhang, F. Wang and S. Liao

Abstract: In the cation of the title compound, [Co(C2H8N2)3][In(C2O4)3(H2O)], the CoIII atom is coordinated by six N atoms from three ethylenediamine molecules. The CoIII-N bond lengths lie in the range 1.956 (4)-1.986 (4) Å. In the anion, the InIII atom is seven-coordinated by six O atoms from three oxalate ligands and by a water molecule. The cations and anions are linked by extensive O-H...O and N-H...O hydrogen bonds, forming a supermolecular network.

Online 17 December 2011


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