[Journal logo]

Volume 68 
Part 1 
Pages m65-m66  
January 2012  

Received 26 November 2011
Accepted 13 December 2011
Online 17 December 2011

[fj2490sup1]
[3d view]

[Cited in]
[Download citation]
Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.007 Å
R = 0.048
wR = 0.119
Data-to-parameter ratio = 16.6
Details
Open access

Tris(ethylenediamine-[kappa]2N,N')cobalt(III) aquatris(oxalato-[kappa]2O1,O2)indate(III)

Zhe Zhang,a Fuxiang Wanga and Shuangquan Liaoa*

aDepartment of Materials and Chemical Engineering, Ministry of Education Key Laboratory of Application Technology of Hainan Superior Resources Chemical Materials, Hainan University, Haikou 570228, Hainan Province, People's Republic of China
Correspondence e-mail: shqliao@126.com

In the cation of the title compound, [Co(C2H8N2)3][In(C2O4)3(H2O)], the CoIII atom is coordinated by six N atoms from three ethylenediamine molecules. The CoIII-N bond lengths lie in the range 1.956 (4)-1.986 (4) Å. In the anion, the InIII atom is seven-coordinated by six O atoms from three oxalate ligands and by a water molecule. The cations and anions are linked by extensive O-H...O and N-H...O hydrogen bonds, forming a supermolecular network.

Related literature

For metal phosphates and germanates templated by metal complexes, see: Du et al. (2004[Du, Y., Yu, J. H. & Xu, R. R. (2004). J. Solid State Chem. 177, 2032-3037.]); Pan et al. (2005[Pan, Q. H., Yu, J. H. & Xu, R. R. (2005). Chem. J. Chin. Univ. 26, 2199-2202.], 2008[Pan, Q. H., Yu, J. H. & Xu, R. R. (2008). Chem. Mater. 20, 370-372.]); Wang et al. (2003a[Wang, Y., Yu, J. H. & Xu, R. R. (2003a). J. Solid State Chem. 170, 176-3037.],b[Wang, Y., Yu, J. H. & Xu, R. R. (2003b). Angew. Chem. Int. Ed. 42, 4089-4092.],c[Wang, Y., Yu, J. H. & Xu, R. R. (2003c). Chem. Eur. J. 9, 5048-5055.]). For coordination polymers templated by metal complexes, see: Pan et al. (2010a[Pan, Q. H., Li, J. Y. & Bu, X.-H. (2010a). Microporous Mesoporous Mater. 132, 453-457.],b[Pan, Q. H., Cheng, Q. & Bu, X.-H. (2010b). CrystEngComm, 12, 4198-4204.], 2011[Pan, Q. H., Cheng, Q. & Bu, X.-H. (2011). Chem. J. Chin. Univ. 32, 527-531.]), Tong & Pan (2011[Tong, J. & Pan, Q. (2011). Acta Cryst. E67, m579-m580.]).

[Scheme 1]

Experimental

Crystal data

  • [Co(C2H8N2)3][In(C2O4)3(H2O)]

  • Mr = 636.14

  • Triclinic, [P \overline 1]

  • a = 7.5161 (15) Å

  • b = 10.921 (2) Å

  • c = 14.450 (3) Å

  • [alpha] = 79.43 (3)°

  • [beta] = 80.13 (3)°

  • [gamma] = 71.25 (3)°

  • V = 1096.1 (4) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 1.89 mm-1

  • T = 293 K

  • 0.3 × 0.2 × 0.18 mm
Data collection

  • Rigaku R-AXIS RAPID-S diffractometer

  • Absorption correction: multi-scan (CrystalClear; Rigaku/MSC, 2002[Rigaku/MSC (2002). CrystalStructure. Rigaku/MSC, The Woodlands, Texas, USA.]) Tmin = 0.6, Tmax = 0.8

  • 11056 measured reflections

  • 4988 independent reflections

  • 4360 reflections with I > 2[sigma](I)

  • Rint = 0.056
Refinement

  • R[F2 > 2[sigma](F2)] = 0.048

  • wR(F2) = 0.119

  • S = 1.10

  • 4988 reflections

  • 300 parameters

  • Only H-atom displacement parameters refined

  • [Delta][rho]max = 1.32 e Å-3

  • [Delta][rho]min = -0.91 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O13-H13A...O12i 0.91 1.79 2.620 (5) 150
O13-H13B...O6ii 0.86 1.84 2.629 (4) 152
N1-H1A...O11iii 0.90 2.17 3.064 (5) 171
N1-H1B...O8iv 0.90 2.14 2.972 (5) 153
N2-H2A...O7v 0.90 2.10 2.935 (5) 155
N2-H2B...O10vi 0.90 2.01 2.838 (5) 152
N3-H3A...O7v 0.90 2.34 3.142 (5) 149
N3-H3A...O3v 0.90 2.37 3.063 (5) 134
N3-H3B...O6iv 0.90 2.06 2.878 (5) 151
N4-H4A...O1iii 0.90 2.26 3.114 (5) 159
N4-H4A...O2iii 0.90 2.49 3.103 (5) 126
N4-H4B...O2 0.90 2.04 2.924 (6) 168
N5-H5A...O8v 0.90 2.09 2.962 (5) 163
N5-H5B...O4 0.90 2.14 2.912 (5) 143
N5-H5B...O2 0.90 2.40 3.099 (5) 135
N6-H6A...O11iii 0.90 2.27 3.040 (5) 143
N6-H6A...O1iii 0.90 2.49 3.279 (5) 147
N6-H6B...O10vi 0.90 2.31 3.105 (5) 147
Symmetry codes: (i) -x+1, -y+1, -z+1; (ii) x+1, y, z; (iii) -x, -y+1, -z+2; (iv) -x, -y, -z+2; (v) -x+1, -y, -z+2; (vi) x, y, z+1.

Data collection: RAPID-AUTO (Rigaku, 1998[Rigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.]); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002[Rigaku/MSC (2002). CrystalStructure. Rigaku/MSC, The Woodlands, Texas, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: FJ2490 ).

Acknowledgements

This work was supported by the Foundation of Hainan University (No. hd09xm69) and the University Scientific Research Foundation of the Education Committee of Hainan Province (No. HJKL2009-16).

References

Du, Y., Yu, J. H. & Xu, R. R. (2004). J. Solid State Chem. 177, 2032-3037.  [ISI] [CrossRef]
Pan, Q. H., Cheng, Q. & Bu, X.-H. (2010b). CrystEngComm, 12, 4198-4204.  [ISI] [CSD] [CrossRef] [ChemPort]
Pan, Q. H., Cheng, Q. & Bu, X.-H. (2011). Chem. J. Chin. Univ. 32, 527-531.  [ChemPort]
Pan, Q. H., Li, J. Y. & Bu, X.-H. (2010a). Microporous Mesoporous Mater. 132, 453-457.  [ISI] [CSD] [CrossRef] [ChemPort]
Pan, Q. H., Yu, J. H. & Xu, R. R. (2005). Chem. J. Chin. Univ. 26, 2199-2202.  [ChemPort]
Pan, Q. H., Yu, J. H. & Xu, R. R. (2008). Chem. Mater. 20, 370-372.  [ISI] [CSD] [CrossRef] [ChemPort]
Rigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2002). CrystalStructure. Rigaku/MSC, The Woodlands, Texas, USA.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Tong, J. & Pan, Q. (2011). Acta Cryst. E67, m579-m580.  [CSD] [CrossRef] [ChemPort] [details]
Wang, Y., Yu, J. H. & Xu, R. R. (2003a). J. Solid State Chem. 170, 176-3037.  [ISI] [CSD] [CrossRef] [ChemPort]
Wang, Y., Yu, J. H. & Xu, R. R. (2003b). Angew. Chem. Int. Ed. 42, 4089-4092.  [ISI] [CSD] [CrossRef] [ChemPort]
Wang, Y., Yu, J. H. & Xu, R. R. (2003c). Chem. Eur. J. 9, 5048-5055.  [CSD] [CrossRef] [PubMed] [ChemPort]

Acta Cryst (2012). E68, m65-m66   [ doi:10.1107/S1600536811053736 ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.