Acta Cryst. (2012). E68, o228 [ doi:10.1107/S1600536811054353 ]
Abstract: The asymmetric unit of the title salt, C7H10N+·C8H5O4-, consists of two 3-methylphenylammonium cations and two hydrogen phthalate anions. There are strong intramolecular O-HO hydrogen bonds in the virtually planar (r.m.s. deviations = 0.054 Å) phthalate anions. In the crystal, the cations and anions are connected via an extensive sytem of N-HO hydrogen bonds into a corrugated layer extended parallel to (001).
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