Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 1 (January 2012)

organic compounds

Acta Cryst. (2012). E68, o228    [ doi:10.1107/S1600536811054353 ]

3-Methyl­anilinium hydrogen phthalate

M.-L. Liu

Abstract: The asymmetric unit of the title salt, C7H10N+·C8H5O4-, consists of two 3-methyl­phenyl­ammonium cations and two hydrogen phthalate anions. There are strong intra­molecular O-H...O hydrogen bonds in the virtually planar (r.m.s. deviations = 0.054 Å) phthalate anions. In the crystal, the cations and anions are connected via an extensive sytem of N-H...O hydrogen bonds into a corrugated layer extended parallel to (001).

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