[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m9  [ doi:10.1107/S1600536811051282 ]


J. Zhao and Y.-L. Jin

Abstract: The structure of the title compound, [Mn(NCS)2(C6H8N2)4], consists of isolated molecules of [Mn(NCS)2(Aim)4] (Aim = 1-allylimidazole), which contain a compressed octahedral MnN6 chromophore (site symmetry \\overline1). The NCS- anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn-N(Aim) and Mn-N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C-H...N interactions contribute to the crystal packing stability.

Online 3 December 2011

Copyright © International Union of Crystallography
IUCr Webmaster