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Volume 68 
Part 1 
Page m37  
January 2012  

Received 16 November 2011
Accepted 1 December 2011
Online 10 December 2011

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.007 Å
Disorder in main residue
R = 0.061
wR = 0.143
Data-to-parameter ratio = 14.4
Details
Open access

catena-Poly[[bis([mu]-2-formyl-6-methoxyphenolato-1:2[kappa]4O1,O6:O1,O2)copper(II)sodium]-[mu]-tetrafluoridoborate-1:1'[kappa]2F:F']

aSchool of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China
Correspondence e-mail: gaoting1218@yahoo.com.cn

In the title heterodinuclear complex, [CuNa(BF4)(C8H7O3)2]n, the CuII ion is four-coordinated by four O atoms of two 2-formyl-6-methoxyphenolate ligands, giving rise to a square-planar geometry. The Na+ ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetrafluoridoborate anions. The tetrafluoridoborate anion links the Na+ ions, forming a one-dimensional structure along [001]. Three F atoms of the tetrafluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790 (11):0.210 (11).

Related literature

For related heterodinuclear complexes, see: Gao et al. (2011[Gao, P., Hou, H.-G., Gao, T., Yang, J.-L. & Yang, Y. (2011). Acta Cryst. E67, m1522.]); Kajiwara et al. (2008[Kajiwara, T., Nakano, M., Takaishi, S. & Yamashita, M. (2008). Inorg. Chem. 47, 8604-8606.]).

[Scheme 1]

Experimental

Crystal data
  • [CuNa(BF4)(C8H7O3)2]

  • Mr = 475.62

  • Monoclinic, P 21 /c

  • a = 9.932 (2) Å

  • b = 19.349 (4) Å

  • c = 9.940 (2) Å

  • [beta] = 105.16 (3)°

  • V = 1843.7 (7) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.28 mm-1

  • T = 293 K

  • 0.21 × 0.18 × 0.16 mm

Data collection
  • Rigaku R-AXIS RAPID diffractometer

  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995[Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.779, Tmax = 0.820

  • 17729 measured reflections

  • 4201 independent reflections

  • 2278 reflections with I > 2[sigma](I)

  • Rint = 0.100

Refinement
  • R[F2 > 2[sigma](F2)] = 0.061

  • wR(F2) = 0.143

  • S = 1.04

  • 4201 reflections

  • 292 parameters

  • 30 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 0.50 e Å-3

  • [Delta][rho]min = -0.34 e Å-3

Table 1
Selected bond lengths (Å)

Cu1-O2 1.888 (3)
Cu1-O3 1.929 (3)
Cu1-O5 1.889 (3)
Cu1-O6 1.936 (3)
Na1-O1 2.615 (3)
Na1-O2 2.377 (3)
Na1-O4 2.614 (4)
Na1-O5 2.370 (3)
Na1-F1 2.215 (7)
Na1-F3' 2.344 (17)
Na1-F4i 2.243 (4)
Symmetry code: (i) [x, -y+{\script{3\over 2}}, z+{\script{1\over 2}}].

Data collection: RAPID-AUTO (Rigaku, 1998[Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.]); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002[Rigaku/MSC (2002). CrystalStructure. Rigaku/MSC Inc., The Woodlands, Texas, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: DIAMOND (Brandenburg, 1999[Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HY2490 ).


Acknowledgements

The authors gratefully acknowledge financial support from Heilongjiang Province (11551334) and the Students Innovation Programme of Heilongjiang University (CX11073).

References

Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Gao, P., Hou, H.-G., Gao, T., Yang, J.-L. & Yang, Y. (2011). Acta Cryst. E67, m1522.  [CSD] [CrossRef] [details]
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
Kajiwara, T., Nakano, M., Takaishi, S. & Yamashita, M. (2008). Inorg. Chem. 47, 8604-8606.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2002). CrystalStructure. Rigaku/MSC Inc., The Woodlands, Texas, USA.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]


Acta Cryst (2012). E68, m37  [ doi:10.1107/S1600536811051713 ]

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