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Acta Cryst. (2012). E68, m10  [ doi:10.1107/S1600536811051063 ]

Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-[kappa]N1]nickel(II) decahydrate

W. Sun, Y. Yu, G. Wang and X. Wu

Abstract: In the title compound, [Ni(C9H6N3O2)2(H2O)4]·10H2O, the NiII ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water molecules, two of which also lie on the twofold rotation axis. In the crystal, the complex molecules and uncoordinated water molecules are linked via intermolecular O-H...N and O-H...O hydrogen bonds, forming a three-dimensional supramolecular network. [pi]-[pi] interactions between the benzene rings provide additional stability of the crystal packing [centroid-centroid distance = 3.792 (2) Å].

Online 3 December 2011


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