Received 19 November 2011
aDepartment of Preventive Medicine, School of Public Health, Jilin University, Changchun 130021, People's Republic of China,bDepartment of Hematology, the First Hospital of Jilin University, Changchun 130021, People's Republic of China, and cSchool of Public Health, Jilin University, Changchun 130021, People's Republic of China
Correspondence e-mail: email@example.com
In the title compound, [Ni(C9H6N3O2)2(H2O)4]·10H2O, the NiII ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water molecules, two of which also lie on the twofold rotation axis. In the crystal, the complex molecules and uncoordinated water molecules are linked via intermolecular O-HN and O-HO hydrogen bonds, forming a three-dimensional supramolecular network. - interactions between the benzene rings provide additional stability of the crystal packing [centroid-centroid distance = 3.792 (2) Å].
For general background to the applications and structures of metal coordination polymers, see: Rowsell & Yaghi (2005); Su et al. (2010); Wang et al. (2009); Zhang & Chen (2008). For a related structure, see: Cui & Zhao (2011).
Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HY2491 ).
The authors thank Jilin University for supporting this work.
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