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Acta Cryst. (2012). E68, m19  [ doi:10.1107/S1600536811051853 ]

catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-[mu]-iodido]]

H.-R. Zhao

Abstract: The title complex, {(C16H12FN2)[PbI3]}n, consists of 1-[(2-fluorobenzylidene)amino]quinolinium cations and a polymeric PbI3- anion formed by face-sharing PbI6 octahedra. These octahedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI3]- fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.

Online 7 December 2011


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