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Volume 68 
Part 1 
Page m19  
January 2012  

Received 28 October 2011
Accepted 1 December 2011
Online 7 December 2011

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.020 Å
R = 0.047
wR = 0.082
Data-to-parameter ratio = 19.7
Details
Open access

catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-[mu]-iodido]]

aSchool of Biochemical and Environmental Engineering, Nanjing Xiaozhuang College, Nanjing 210017, People's Republic of China
Correspondence e-mail: zhaohairong5@yahoo.com.cn

The title complex, {(C16H12FN2)[PbI3]}n, consists of 1-[(2-fluorobenzylidene)amino]quinolinium cations and a polymeric PbI3- anion formed by face-sharing PbI6 octahedra. These octahedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI3]- fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.

Related literature

For second-order non-linear optical (NLO) properties, pyroelectricity, ferroelectricity and triboluminescence of inorganic-organic hybrid materials, see: Guloy et al. (2001[Guloy, A. M., Tang, Z. J., Miranda, P. B. & Srdanov, V. I. (2001). Adv. Mater. 13, 833-837.]); Horiuchi et al. (2010[Horiuchi, S., Tokunaga, Y., Giovannetti, G., Picozzi, S., Itoh, H., Shimano, R., Kumai, R. & Tokura, Y. (2010). Nature (London), 463, 789-792.]); Chen et al. (2001[Chen, X. F., Duan, C. Y., Zhu, X. H., You, X. Z., Raj, S. S. S., Fun, H. K. & Wu, J. (2001). Mater. Chem. Phys. 72, 11-15.]). For related structures, see: Bi et al. (2008[Bi, W., Louvain, N., Mercier, N., Luc, J., Rau, I., Kajzar, F. & Sahraoui, B. (2008). Adv. Mater. 20, 1013-1017.]); Zhang et al. (2006[Zhang, Z. J., Guo, G. C., Xu, G., Fu, M. L., Zou, J. P. & Huang, J. S. (2006). Inorg. Chem. 45, 10028-10030.]); Duan et al. (2011[Duan, H. B., Zhao, H. R., Ren, X. M., Zhou, H., Tian, Z. F. & Jin, W. Q. (2011). Dalton Trans. 40, 1672-1683.]); Zhao et al. (2010[Zhao, H. R., Li, D. P., Ren, X. M., Song, Y. & Jin, W. Q. (2010). J. Am. Chem. Soc. 132, 18-19.]).

[Scheme 1]

Experimental

Crystal data
  • (C16H12FN2)[PbI3]

  • Mr = 839.17

  • Orthorhombic, P b c a

  • a = 20.888 (4) Å

  • b = 7.9112 (15) Å

  • c = 25.197 (5) Å

  • V = 4163.8 (14) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 12.56 mm-1

  • T = 296 K

  • 0.04 × 0.02 × 0.01 mm

Data collection
  • Siemens SMART CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 2002[Sheldrick, G. M. (2002). SADABS. University of Göttingen, Germany.]) Tmin = 0.747, Tmax = 0.882

  • 30847 measured reflections

  • 4090 independent reflections

  • 1770 reflections with I > 2[sigma](I)

  • Rint = 0.156

Refinement
  • R[F2 > 2[sigma](F2)] = 0.047

  • wR(F2) = 0.082

  • S = 0.96

  • 4090 reflections

  • 208 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.96 e Å-3

  • [Delta][rho]min = -0.95 e Å-3

Data collection: SMART (Siemens, 1996[Siemens (1996). SMART and SAINT. Siemens Analytical X-ray Instrument Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Siemens, 1996[Siemens (1996). SMART and SAINT. Siemens Analytical X-ray Instrument Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: IM2337 ).


Acknowledgements

The authors thank the Natural Science Foundation of China for financial support (grant No. 21002096).

References

Bi, W., Louvain, N., Mercier, N., Luc, J., Rau, I., Kajzar, F. & Sahraoui, B. (2008). Adv. Mater. 20, 1013-1017.  [ISI] [CSD] [CrossRef] [ChemPort]
Chen, X. F., Duan, C. Y., Zhu, X. H., You, X. Z., Raj, S. S. S., Fun, H. K. & Wu, J. (2001). Mater. Chem. Phys. 72, 11-15.  [ISI] [CrossRef] [ChemPort]
Duan, H. B., Zhao, H. R., Ren, X. M., Zhou, H., Tian, Z. F. & Jin, W. Q. (2011). Dalton Trans. 40, 1672-1683.  [CSD] [CrossRef] [ChemPort] [PubMed]
Guloy, A. M., Tang, Z. J., Miranda, P. B. & Srdanov, V. I. (2001). Adv. Mater. 13, 833-837.  [ISI] [CSD] [CrossRef] [ChemPort]
Horiuchi, S., Tokunaga, Y., Giovannetti, G., Picozzi, S., Itoh, H., Shimano, R., Kumai, R. & Tokura, Y. (2010). Nature (London), 463, 789-792.  [ISI] [CSD] [CrossRef] [ChemPort] [PubMed]
Sheldrick, G. M. (2002). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Siemens (1996). SMART and SAINT. Siemens Analytical X-ray Instrument Inc., Madison, Wisconsin, USA.
Zhang, Z. J., Guo, G. C., Xu, G., Fu, M. L., Zou, J. P. & Huang, J. S. (2006). Inorg. Chem. 45, 10028-10030.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Zhao, H. R., Li, D. P., Ren, X. M., Song, Y. & Jin, W. Q. (2010). J. Am. Chem. Soc. 132, 18-19.  [ISI] [CSD] [CrossRef] [ChemPort] [PubMed]


Acta Cryst (2012). E68, m19  [ doi:10.1107/S1600536811051853 ]

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