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Acta Cryst. (2012). E68, m6-m7 [ doi:10.1107/S1600536811051245 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-ferrocenecarboxylato)bis[aquabis(ferrocenecarboxylato)methanolerbium(III)] methanol disolvateAbstract: In the centrosymmetric title coordination compound, [Er2{Fe(C5H5)(C6H4O2)}6(CH3OH)2(H2O)2]·2CH3OH, the two ErIII ions are bridged by two ferrocenecarboxylate anions as asymmetrically bridging ligands, leading to dimeric cores. The ErIII ion has a distorted dodecahedral coordination with six coordinating O atoms derived from the ferrocenecarboxylate ligands and two coordinated O atoms from one water molecule and one methanol molecule. The asymmetric unit comprises a half of the complex molecule and a methanol solvent molecule. Intramolecular O-H
O and C-HO interactions occur. In the crystal, molecules are linked by intermolecular O-HO hydrogen bonds and C-HO as well as C-H![[pi]](/logos/entities/pi_rmgif.gif)
interactions.
Online 3 December 2011
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