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Acta Cryst. (2012). E68, m86  [ doi:10.1107/S1600536811054316 ]

{N'-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate

B.-L. Liu, D.-M. Dong, X.-Y. Hua and J.-W. Zhu

Abstract: The title mononuclear complex, [Cu(C18H12N2O2)(C12H8N2)]·CH3OH, contains one N'-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand (L2-), a Cu2+ cation, one 1,10-phenanthroline ligand and a methanol solvent molecule. The CuII ion adopts a CuO2N3 distorted square-pyramidal coordination. An O-H...O hydrogen bond is formed between the methanol solvent molecule and the hydrazide O atom of the L2- ligand.

Online 23 December 2011


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