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Acta Cryst. (2012). E68, m18 [ doi:10.1107/S160053681105152X ]
![[mu]](/logos/entities/mu_rmgif.gif)
-di-2-pyridyl disulfide-![[kappa]](/logos/entities/kappa_rmgif.gif)
3N,S:N')di-3-iodido-di-2-iodido-tetracopper(I)Abstract: In the centrosymmetric tetranuclear title compound, [Cu4I4(C10H8N2S2)2], there are two different CuI atoms with tetrahedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second CuI atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the CuI atoms form a tetranuclear structure.
Online 7 December 2011
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