[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m12-m13  [ doi:10.1107/S1600536811051348 ]

Bis([mu]-N-benzyl-N-furfuryldithiocarbamato)-1:2[kappa]3S,S':S';2:1[kappa]3S,S':S'-bis[(N-benzyl-N-furfuryldithiocarbamato-[kappa]2S,S')cadmium]

R. Kant, V. K. Gupta, K. Kapoor, P. Valarmathi and S. Thirumaran

Abstract: In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the CdII atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).

Online 3 December 2011


Copyright © International Union of Crystallography
IUCr Webmaster