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Acta Cryst. (2012). E68, m33-m34  [ doi:10.1107/S160053681105207X ]

Bis(tetraphenylphosphonium) bis[N-(trifluoromethylsulfonyl)dithiocarbimato(2-)-[kappa]2S,S']zincate(II)

P. S. Pinto, M. M. M. Rubinger, S. Guilardi, D. A. Paixão and M. R. L. Oliveira

Abstract: The title salt, (C24H20P)2[Zn(C2F3NO2S3)2], consists of a complex dianion and two tetraphenylphosphonium cations. The ZnII ion displays a distorted tetrahedral coordination environment with four S atoms from two S,S'-chelated N-(trifluoromethylsulfonyl)dithiocarbimate anions. In the crystal, besides the ionic interaction of the oppositely charged ions, intermolecular C-H...O interactions between cations and anions are observed. One of the cations interacts with an inversion-related equivalent by [pi]-[pi] stacking between phenyl rings, with a centroid-centroid distance of 3.932 (4) Å.

Online 10 December 2011


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