Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 1 (January 2012)

metal-organic compounds

Acta Cryst. (2012). E68, m84-m85    [ doi:10.1107/S1600536811054183 ]


S.-G. Hou and M.-F. Jin

Abstract: In the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)]n, the CdII cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethyl­isophthalate (TMIPA) anions, and is further coordinated by one carboxyl­ate O atom from a third TMIPA anion, forming a distorted penta­gonal-bipyramidal geometry. Each TMIPA anion bridges three CdII cations, forming polymeric complex sheets parallel to (001). Weak C-H...O hydrogen bonding occurs between adjacent sheets.

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