Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 1 (January 2012)

metal-organic compounds

 

Poly[(2,2'-bipyridine-²N,N')(₃-2,4,6-trimethylisophthalato-⁵O¹,O^1':O¹:O³,O^3')cadmium]

S.-G. Hou and M.-F. Jin

Abstract: In the crystal structure of the polymeric title complex, [Cd(C₁₁H₁₀O₄)(C₁₀H₈N₂)]_n, the Cd^II cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal-bipyramidal geometry. Each TMIPA anion bridges three Cd^II cations, forming polymeric complex sheets parallel to (001). Weak C-HO hydrogen bonding occurs between adjacent sheets.

	Hyper-Text Markup Language (HTML) file (76.7 kbytes) [ doi:10.1107/S1600536811054183/xu5394sup0.html ] Supplementary materials
	MDL mol file (9.9 kbytes) [ doi:10.1107/S1600536811054183/xu5394Isup3.mol ] Supplementary material

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