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Volume 68 
Part 1 
Pages m84-m85  
January 2012  

Received 23 November 2011
Accepted 16 December 2011
Online 23 December 2011

Key indicators
Single-crystal X-ray study
T = 298 K
Mean [sigma](C-C) = 0.007 Å
R = 0.045
wR = 0.098
Data-to-parameter ratio = 17.0
Details
Open access

Poly[(2,2'-bipyridine-[kappa]2N,N')([mu]3-2,4,6-trimethylisophthalato-[kappa]5O1,O1':O1:O3,O3')cadmium]

aCollege of Chemical and Environmental Engineering, Anyang Institute of Technology, Anyang 455000, People's Republic of China
Correspondence e-mail: aymeifangjin@163.com

In the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)]n, the CdII cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal-bipyramidal geometry. Each TMIPA anion bridges three CdII cations, forming polymeric complex sheets parallel to (001). Weak C-H...O hydrogen bonding occurs between adjacent sheets.

Related literature

For applications of functional metal-organic frameworks, see: Evans & Lin (2002[Evans, O. R. & Lin, W. (2002). Acc. Chem. Res. 35, 511-522.]); Chen et al. (2010[Chen, B., Xiang, S. & Qian, G. (2010). Acc. Chem. Res 43, 1115-1124.]); Leong & Vittal (2011[Leong, W. L. & Vittal, J. J. (2011). Chem. Rev. 111, 688-764.]); Sun et al. (2011[Sun, J., Dai, F., Yuan, W., Bi, W., Zhao, X., Sun, W. & Sun, D. (2011). Angew. Chem., Int. Ed. 50, 7061-7064]). For related structures, see: Ma et al. (2008[Ma, L., Lee, J. Y., Li, J. & Lin, W. (2008). Inorg. Chem. 47, 3955-3957.]); Zhang et al. (2008[Zhang, J.-Y., Cheng, A.-L., Yue, Q., Sun, W.-W. & Gao, E.-Q. (2008). Chem. Commun. pp. 847-849.]); Zhou et al. (2003[Zhou, Y.-F., Zhao, Y.-J., Sun, D.-F., Weng, J.-B., Cao, R. & Hong, M.-C. (2003). Polyhedron, 22, 1231-1235.]); Zhang et al. (2003[Zhang, L.-Y., Liu, G.-F., Zheng, S.-L., Ye, B.-H., Zhang, X.-M. & Chen, X.-M. (2003). Eur. J. Inorg. Chem. pp. 2965-2971]); He et al. (2010[He, H.-Y., David, C., Fangna Dai, F. N., Zhao, X.-L., Zhang, G.-Q., Ma, H.-Q. & Sun, D.-F. (2010). Cryst. Growth Des. 10, 895-902.]); Liu et al. (2008[Liu, X., Liu, K., Yang, Y. & Li, B. (2008). Inorg. Chem. Commun. 11, 1273-1275.]). For our previous work, see: Dai et al. (2008[Dai, F., He, H. & Sun, D. (2008). J. Am. Chem. Soc. 130, 14064-14065], 2009[Dai, F., He, H. & Sun, D. (2009). Inorg. Chem. 48, 4613-4615.]); Zhao et al. (2009[Zhao, X., He, H., Hu, T., Dai, F. & Sun, D. (2009). Inorg. Chem. 48, 8057-8059.]).

[Scheme 1]

Experimental

Crystal data
  • [Cd(C11H10O4)(C10H8N2)]

  • Mr = 474.77

  • Orthorhombic, P b c a

  • a = 13.1985 (8) Å

  • b = 15.5714 (9) Å

  • c = 18.1926 (11) Å

  • V = 3738.9 (4) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 1.20 mm-1

  • T = 298 K

  • 0.15 × 0.10 × 0.10 mm

Data collection
  • Bruker SMART APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.841, Tmax = 0.890

  • 14349 measured reflections

  • 4299 independent reflections

  • 2454 reflections with I > 2[sigma](I)

  • Rint = 0.054

Refinement
  • R[F2 > 2[sigma](F2)] = 0.045

  • wR(F2) = 0.098

  • S = 0.99

  • 4299 reflections

  • 253 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.51 e Å-3

  • [Delta][rho]min = -0.63 e Å-3

Table 1
Selected bond lengths (Å)

Cd1-N1 2.393 (4)
Cd1-N2 2.334 (4)
Cd1-O1 2.607 (3)
Cd1-O2i 2.317 (3)
Cd1-O2 2.372 (3)
Cd1-O3ii 2.347 (3)
Cd1-O4ii 2.396 (3)
Symmetry codes: (i) -x+1, -y+1, -z+1; (ii) [-x+{\script{3\over 2}}, y+{\script{1\over 2}}, z].

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C4-H4A...O1iii 0.93 2.32 3.240 (6) 169
C8-H8A...O3iii 0.93 2.39 3.251 (6) 155
Symmetry code: (iii) [x-{\script{1\over 2}}, y, -z+{\script{3\over 2}}].

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: DIAMOND (Brandenburg, 2008[Brandenburg, K. (2008). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5394 ).


Acknowledgements

This work was supported financially by Anyang Institute of Technology, China.

References

Brandenburg, K. (2008). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Chen, B., Xiang, S. & Qian, G. (2010). Acc. Chem. Res 43, 1115-1124.  [CrossRef] [ChemPort] [PubMed]
Dai, F., He, H. & Sun, D. (2008). J. Am. Chem. Soc. 130, 14064-14065  [CrossRef] [PubMed] [ChemPort]
Dai, F., He, H. & Sun, D. (2009). Inorg. Chem. 48, 4613-4615.  [CrossRef] [PubMed] [ChemPort]
Evans, O. R. & Lin, W. (2002). Acc. Chem. Res. 35, 511-522.  [ISI] [CrossRef] [PubMed] [ChemPort]
He, H.-Y., David, C., Fangna Dai, F. N., Zhao, X.-L., Zhang, G.-Q., Ma, H.-Q. & Sun, D.-F. (2010). Cryst. Growth Des. 10, 895-902.  [CrossRef] [ChemPort]
Leong, W. L. & Vittal, J. J. (2011). Chem. Rev. 111, 688-764.  [ISI] [CrossRef] [ChemPort] [PubMed]
Liu, X., Liu, K., Yang, Y. & Li, B. (2008). Inorg. Chem. Commun. 11, 1273-1275.  [ISI] [CSD] [CrossRef]
Ma, L., Lee, J. Y., Li, J. & Lin, W. (2008). Inorg. Chem. 47, 3955-3957.  [ISI] [CrossRef] [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Sun, J., Dai, F., Yuan, W., Bi, W., Zhao, X., Sun, W. & Sun, D. (2011). Angew. Chem., Int. Ed. 50, 7061-7064
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]
Zhang, J.-Y., Cheng, A.-L., Yue, Q., Sun, W.-W. & Gao, E.-Q. (2008). Chem. Commun. pp. 847-849.  [CSD] [CrossRef]
Zhang, L.-Y., Liu, G.-F., Zheng, S.-L., Ye, B.-H., Zhang, X.-M. & Chen, X.-M. (2003). Eur. J. Inorg. Chem. pp. 2965-2971
Zhao, X., He, H., Hu, T., Dai, F. & Sun, D. (2009). Inorg. Chem. 48, 8057-8059.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Zhou, Y.-F., Zhao, Y.-J., Sun, D.-F., Weng, J.-B., Cao, R. & Hong, M.-C. (2003). Polyhedron, 22, 1231-1235.  [ISI] [CSD] [CrossRef] [ChemPort]


Acta Cryst (2012). E68, m84-m85   [ doi:10.1107/S1600536811054183 ]

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