![[HTML version]](/e/graphics/htmlborder.gif)
![[PDF version]](/e/graphics/pdfborder.gif)
![[CIF]](/e/graphics/cifborder.gif)
![[3d view]](/e/graphics/3dviewborder.gif)
![[Structure Factors]](/e/graphics/structurefactorsborder.gif)
![[Supplementary Material]](/e/graphics/supplementarymaterialsborder.gif)
![[CIF check Report]](/e/graphics/checkcifborder.gif)
![[Issue contents]](/e/graphics/issuecontentsborder.gif)
![[Open access]](/e/graphics/free.gif)
![[Contents scheme]](xu5400contents.gif)
Acta Cryst. (2012). E68, m21-m22 [ doi:10.1107/S1600536811051956 ]
![[mu]](/logos/entities/mu_rmgif.gif)
2-oxalato-![[kappa]](/logos/entities/kappa_rmgif.gif)
4O1,O2:O1',O2')bis(3-pyridine-2,4-dicarboxylato-4N,O1:O1':O4)dicerium(III)] monohydrate]Abstract: In the polymeric title compound, {[Ce2(C7H3NO4)2(C2O4)(H2O)6]·H2O}n, the Ce3+ cation is nine-coordinated in a distorted CeNO8 tricapped trigonal-prismatic geometry, formed by three pyridine-2,4-dicarboxylate anions, one oxalate anion and three water molecules. The mid-point of the oxalate anion is located on an inversion center. The oxalate and pyridine-2,4-dicarboxylate anions bridge the Ce3+ cations, forming a two-dimensional polymeric complex parallel to (010). Intermolecular classical O-H
O hydrogen bonding and weak C-HO hydrogen bonding are present in the crystal structure and ![[pi]](/logos/entities/pi_rmgif.gif)
- stacking [centroid-centroid distance = 3.558 (2) Å] is observed between parallel pyridine rings of adjacent molecules. The uncoordinated water molecule shows an occupancy of 0.5.
Online 7 December 2011
Copyright © International Union of Crystallography
IUCr Webmaster