Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 1 (January 2012)

organic compounds

zq2147 scheme

Acta Cryst. (2012). E68, o199-o200 [ doi:10.1107/S1600536811054080 ]

(E)-1-[2-(Methylsulfanyl)phenyl]-2-({(E)-2-[2-(methylsulfanyl)phenyl]hydrazinylidene}(nitro)methyl)diazene

K. G. von Eschwege, F. Muller and E. C. Hosten

Abstract: In the title compound, C₁₅H₁₅N₅O₂S₂, the phenyl rings make dihedral angles of 4.03 (4) and 9.77 (5)° with the plane defined by the central N-N-C-N-N atoms (r.m.s. deviation = 0.010 Å). The C-S-C-C torsion angles of the methylsulfanyl groups with their respective phenyl rings are -7.47 (13) and -72.07 (13)°. The shortest centroid-centroid distance of 3.707 Å occurs between the two [pi] -systems N-N-C-N-N and the benzene ring in the diazene 1-position. The H atom bound to the N atom is involved in intramolecular N-HN and N-HS contacts, while the nitro O atoms are involved in intermolecular C-HO contacts.


	Hyper-Text Markup Language (HTML) file (70.5 kbytes) [ doi:10.1107/S1600536811054080/zq2147sup0.html ] Supplementary materials

	Chemical Markup Language (CML) file (6.7 kbytes) [ doi:10.1107/S1600536811054080/zq2147Isup3.cml ] Supplementary material

Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

Search: From to Advanced search