Acta Crystallographica Section E

Volume 68, Part 2 (February 2012)

organic compounds

ld2041 scheme

Acta Cryst. (2012). E68, o310-o311 [ doi:10.1107/S1600536811055279 ]

(3-Chlorophenyl){2-ethoxy-5-[(Z)-hydroxy(phenyl)methylidene]cyclopenta-1,3-dien-1-yl}methanone

M.-L. Tintas, R. A. Varga, I. Grosu and E. Bogdan

Abstract: The title compound, C₂₁H₁₇ClO₃, which crystallizes as one of two possible oxo/hydroxy-fulvene prototropic tautomers, possesses a strong intramolecular O-HO hydrogen bond that closes a seven-membered ring. The dihedral angles between the central five-membered ring and two pendant rings are 55.05 (9) and 44.51 (10)°. The crystal packing is characterized by weak intermolecular C-HO interactions between an H atom of the oxymethylene unit and the carbonyl group of an adjacent molecule, resulting in formation of chains of molecules along the a axis.


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