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Acta Cryst. (2012). E68, o560-o561  [ doi:10.1107/S1600536812003169 ]

7'-(2,5-Dimethoxyphenyl)-1',3',5',6',7',7a'-hexahydrodispiro[indan-2,5'-pyrrolo[1,2-c][1,3]thiazole-6',2''-indan]-1,3,1''-trione

A. C. Wei, M. A. Ali, T. S. Choon, I. A. Razak and S. Arshad

Abstract: In the title compound, C30H25NO5S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intramolecular C-H...O interactions stabilize the molecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexahydropyrrolo[1,2-c]thiazole ring [r.m.s deviation of 0.0393 (1) Å] makes dihedral angles of 60.92 (5), 88.33 (4) and 84.12 (4)° with the terminal benzene ring and the mean planes of the mono and di-oxo substituted indan rings, respectively. Molecules are linked by intermolecular C-H...O interactions into a three-dimensional network. In addition, C-H...[pi] and [pi]-[pi] interactions [centroid-to-centroid distance = 3.4084 (8) Å] further stabilize the crystal structure.

Online 4 February 2012


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