Acta Crystallographica Section E

Volume 68, Part 3 (March 2012)


organic compounds



zs2183 scheme

Acta Cryst. (2012). E68, o902-o903    [ doi:10.1107/S1600536812007921 ]

(Z)-4-(2-Hydroxybenzylidene)-1-methyl-2-phenyl-1H-imidazol-5(4H)-one

M.-J. Chang, H.-Y. Tsai, T.-C. Fang, M.-H. Luo and K.-Y. Chen

Abstract: In the title compound, C17H14N2O2, the asymmetric unit comprises two molecules that are comformationally similar [the dihedral angles between the phenyl rings in each are 46.35 (2) and 48.04 (3)°], with the conformation stabilized by intramolecular O-H...N hydrogen bonds, which generate S(7) rings. In the crystal, inversion-related molecules are linked by pairs of weak C-H...O hydrogen bonds, forming dimers with an R22(16) graph-set motif. Weak inter-ring [pi]-[pi] stacking is observed in the structure, the shortest centroid-to-centroid distance being 3.7480 (13) Å.


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