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Acta Cryst. (2012). E68, m416  [ doi:10.1107/S1600536812010021 ]

Bis(1H-benzimidazole-[kappa]N3)bis[2-(naphthalen-1-yl)acetato-[kappa]2O,O']nickel(II) monohydrate

F.-J. Yin, L.-J. Han, Z. Hong, X.-Y. Xu and L. Ren

Abstract: In the title compound, [Ni(C12H9O2)2(C7H6N2)2]·H2O, The NiII cation is located on a twofold rotation axis and is six-coordinated in a distorted NiN2O4 octahedral geometry. The asymmetric unit consists of a nickel(II) ion, one 2-(naphthalen-1-yl)acetate anion, a neutral benzotriazole ligand and one half of a lattice water molecule. The crystal packing is stabilized by O-H...O and N-H...O hydrogen bonds. The title compound is isotypic with its CdII analogue.

Online 14 March 2012


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