Acta Crystallographica Section E

Volume 68, Part 4 (April 2012)

organic compounds

hg5198 scheme

Acta Cryst. (2012). E68, o1216 [ doi:10.1107/S1600536812012652 ]

Benzyl 2-methyl-3-[(E)-(thiophen-2-yl)methylidene]dithiocarbazate

S. K. S. Hazari, B. K. Dey, T. G. Roy, B. Ganguly, S. W. Ng and E. R. T. Tiekink

Abstract: In the title compound, C₁₄H₁₄N₂S₃, the thione S atom and methyl group are syn, as are the two thioether S atoms. The molecule is twisted, the dihedral angles between the central (C₂N₂S₂) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively. In the crystal, molecules assemble into a three-dimensional architecture via C-H [pi] interactions, involving both the five- and six-membered rings as acceptors, as well as SS interactions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings.


	Hyper-Text Markup Language (HTML) file (63.3 kbytes) [ doi:10.1107/S1600536812012652/hg5198sup0.html ] Supplementary materials

	Chemical Markup Language (CML) file (5.4 kbytes) [ doi:10.1107/S1600536812012652/hg5198Isup3.cml ] Supplementary material

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