Acta Crystallographica Section E

Volume 68, Part 4 (April 2012)

organic compounds

sj5210 scheme

Acta Cryst. (2012). E68, o1079 [ doi:10.1107/S1600536812010707 ]

N'-(5-Chloro-2-hydroxybenzylidene)-4-methoxybenzohydrazide

Y. Tan

Abstract: The asymmetric unit of the title compound, C₁₅H₁₃ClN₂O₃, contains two independent hydrazone molecules. Each molecule adopts an E configuration with respect to the methylidene unit and forms an intramolecular O-HN hydrogen bond. The principal difference between the two unique molecules is the relative orientation of the two benzene rings, the dihedral angles between them being 4.0 (3) and 65.9 (3)°, respectively. In the crystal, molecules are linked through N-HO hydrogen bonds, forming chains running along the c axis.


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