Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 4 (April 2012)

metal-organic compounds

Acta Cryst. (2012). E68, m351-m352    [ ]


H. Hao, B. Zhu and J. Yi

Abstract: The mol­ecular structure of the title compound, [Al(CH3)2(C22H26NO)], displays a monomer with the AlIII atom in a distorted tetra­hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O-Al-N bite angle of the chelating ligand is 94.14 (9)°. The O-C-C-C-N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak inter­molecular C-H...O inter­actions are observed.

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