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[Contents scheme]

Acta Cryst. (2012). E68, o2514
[ doi:10.1107/S1600536812032230 ]

4-Cyano-1-methylpyridinium iodide

M. N. Kammer, L. V. Koplitz and J. T. Mague

Abstract: In the crystal structure of the title compound, C7H7N2+·I-, the cations form inversion-related dimers via weak pairwise C-H...N hydrogen bonds. In the dimers, the pyridinium rings are parallel to one another with their mean planes separated by a normal distance of ca 0.28 Å. Weak C-H...N interactions between adjacent dimers generate a layer lying parallel to (10-1). The remaining H atoms form C-H...I interactions, which link the layers into a three-dimensional structure.


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