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Acta Cryst. (2012). E68, m1044
[ doi:10.1107/S1600536812030577 ]

[N,N'-Bis(2,3,4-trimethoxybenzylidene)ethane-1,2-diamine-[kappa]2N,N']dibromidomercury(II)

A. D. Khalaji, M. Dusek and K. Fejfarová

Abstract: In the title compound, [HgBr2(C22H28N2O6)], the HgII ion is bonded to two Br- ions and two N atoms of the chelating Schiff base ligand in a distorted tetrahedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the central N,N'-dimethylethylenediamine part of the ligand is 2.3 (11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component refined to 0.208 (3).


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