Acta Cryst. (2012). E68, m1101-m1102
[ doi:10.1107/S1600536812032229 ]

(Ethanolato-O)[N'-(3-methoxy-2-oxidobenzylidene-O²)benzohydrazidato-²N',O]oxidovanadium(V)

X.-H. Chen, Q.-J. Wu, L.-J. Chen and M.-X. Yang

Abstract: In the title complex, [V(C₁₅H₁₂N₂O₄)(C₂H₅O)O], the V^V ion is coordinated by an oxide O atom, an ethanolate anion and two O atoms and one N atom from the tridentate benzohydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intramolecular O-HN hydrogen bond occurs in the benzohydrazidate ligand. Weak intermolecular C-HO hydrogen bonding is present in the crystal.

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