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Acta Cryst. (2012). E68, o2752
[ doi:10.1107/S1600536812035520 ]

Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate

B. K. Dey, S. Suarez, B. Ganguly, F. Doctorovich and T. G. Roy

Abstract: In the title compound, C14H14N2OS2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C4N2S2), indicating a twisted conformation for the molecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C-H...[pi] interactions involving the phenyl ring are observed.

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