Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)

organic compounds

Acta Cryst. (2012). E68, o2695-o2696    [ doi:10.1107/S1600536812034794 ]

1-[(4-Chloro­phen­yl)(phen­yl)meth­yl]piperazine-1,4-diium bis­(trichloro­acetate)-trichloro­acetic acid (1/1)

Y. Song, C. S. Chidan Kumar, M. Akkurt, S. Chandraju and H. Li

Abstract: In the title salt adduct, C17H21ClN22+·2C2Cl3O2-·C2HCl3O2, the Cl atom of the dication is disordered over two positions in a 0.915 (3):0.085 (3) ratio. The Cl atoms in the trichloroacetate anions and trichloroacetic acid molecule are also disordered, with refined site-occupation factors of 0.59 (3):0.41 (3), 0.503 (12):0.417 (12) and 0.653 (12):0.347 (12). The piperazine ring adopts a chair conformation, with puckering parameters QT = 0.587 (3) Å, [theta] = 2.6 (2) and [Phi] 334 (6)°. In the crystal, neighbouring mol­ecules are linked by N-H...O, O-H...O, N-H...Cl, C-H...O and C-H...Cl hydrogen bonds, forming a three-dimensional network.

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