Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)

organic compounds

 

1-[(4-Chlorophenyl)(phenyl)methyl]piperazine-1,4-diium bis(trichloroacetate)-trichloroacetic acid (1/1)

Y. Song, C. S. Chidan Kumar, M. Akkurt, S. Chandraju and H. Li

Abstract: In the title salt adduct, C₁₇H₂₁ClN₂²⁺·2C₂Cl₃O₂^-·C₂HCl₃O₂, the Cl atom of the dication is disordered over two positions in a 0.915 (3):0.085 (3) ratio. The Cl atoms in the trichloroacetate anions and trichloroacetic acid molecule are also disordered, with refined site-occupation factors of 0.59 (3):0.41 (3), 0.503 (12):0.417 (12) and 0.653 (12):0.347 (12). The piperazine ring adopts a chair conformation, with puckering parameters Q_T = 0.587 (3) Å, = 2.6 (2) and 334 (6)°. In the crystal, neighbouring molecules are linked by N-HO, O-HO, N-HCl, C-HO and C-HCl hydrogen bonds, forming a three-dimensional network.

	Hyper-Text Markup Language (HTML) file [ doi:10.1107/S1600536812034794/fj2574sup0.html ] Supplementary materials
	Chemical Markup Language (CML) file (9.8 kbytes) [ doi:10.1107/S1600536812034794/fj2574Isup3.cml ] Supplementary material

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