Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)

organic compounds

gg2090 scheme

Acta Cryst. (2012). E68, o2631-o2632 [ doi:10.1107/S160053681203396X ]

[1-Methoxy-3-(pyridin-2-yl)indolizin-2-yl](pyridin-2-yl)methanone

T. Kloubert, R. Kretschmer, H. Görls and M. Westerhausen

Abstract: Methylation of [1-hydroxy-3-(pyridin-2-yl)indolizin-2-yl](pyridin-2-yl)methanone was performed via metalation with potassium tert-butanolate in toluene and a subsequent metathesis reaction with methyl iodide yielded the yellow title compound, C₂₀H₁₅N₃O₂. The substituents at the indolizine unit are twisted [the indolizine ring system makes dihedral angles of 34.67 (7) and 77.49 (5)°, respectively, with the pyridyl and pyridinoyl rings] with single bonds between the central unit and the attached pyridine ring [1.459 (3) Å] and the pyridinoyl group [1.483 (3) Å]. There are no classical hydrogen bonds in the crystal structure.


	Hyper-Text Markup Language (HTML) file [ doi:10.1107/S160053681203396X/gg2090sup0.html ] Supplementary materials

	Chemical Markup Language (CML) file (6.5 kbytes) [ doi:10.1107/S160053681203396X/gg2090Isup3.cml ] Supplementary material

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