Acta Cryst. (2012). E68, m1206-m1207
[ doi:10.1107/S1600536812036367 ]
Abstract: The title compound, [Cu(C12H8N2)(C18H15P)2]2[Mo6O19], was obtained by co-crystallization of the mixed-ligand copper complex cation (1,10-phenanthroline)bis(triphenylphosphane)copper(I), [Cu(phen)(PPh3)2]+, with the Lindquist polyanion [Mo6O19]2-. The asymmetric unit consists of half a Lindquist anion and one [Cu(phen)(PPh3)2]+ cationic complex. In the cation, there are intramolecular - interactions [centroid-centroid distances = 3.617 (2) and 3.7272 (18) Å]. This inorganic-organic adduct is connected by C-HO hydrogen bonds, forming a two dimensional network lying in the ab plane. These networks are connected by C-H interactions into a three-dimensional structure.
Copyright © International Union of Crystallography