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Acta Cryst. (2012). E68, m1206-m1207
[ doi:10.1107/S1600536812036367 ]

Bis[(1,10-phenanthroline-[kappa]2N,N')bis(triphenylphosphane-[kappa]P)copper(I)] nonadecaoxidohexamolybdate(VI)

F. Gschwind and M. Jansen

Abstract: The title compound, [Cu(C12H8N2)(C18H15P)2]2[Mo6O19], was obtained by co-crystallization of the mixed-ligand copper complex cation (1,10-phenanthroline)bis(triphenylphosphane)copper(I), [Cu(phen)(PPh3)2]+, with the Lindquist polyanion [Mo6O19]2-. The asymmetric unit consists of half a Lindquist anion and one [Cu(phen)(PPh3)2]+ cationic complex. In the cation, there are intramolecular [pi]-[pi] interactions [centroid-centroid distances = 3.617 (2) and 3.7272 (18) Å]. This inorganic-organic adduct is connected by C-H...O hydrogen bonds, forming a two dimensional network lying in the ab plane. These networks are connected by C-H...[pi] interactions into a three-dimensional structure.


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