Acta Cryst. (2012). E68, m1206-m1207
[ doi:10.1107/S1600536812036367 ]

Bis[(1,10-phenanthroline-²N,N')bis(triphenylphosphane-P)copper(I)] nonadecaoxidohexamolybdate(VI)

F. Gschwind and M. Jansen

Abstract: The title compound, [Cu(C₁₂H₈N₂)(C₁₈H₁₅P)₂]₂[Mo₆O₁₉], was obtained by co-crystallization of the mixed-ligand copper complex cation (1,10-phenanthroline)bis(triphenylphosphane)copper(I), [Cu(phen)(PPh₃)₂]⁺, with the Lindquist polyanion [Mo₆O₁₉]^2-. The asymmetric unit consists of half a Lindquist anion and one [Cu(phen)(PPh₃)₂]⁺ cationic complex. In the cation, there are intramolecular - interactions [centroid-centroid distances = 3.617 (2) and 3.7272 (18) Å]. This inorganic-organic adduct is connected by C-HO hydrogen bonds, forming a two dimensional network lying in the ab plane. These networks are connected by C-H interactions into a three-dimensional structure.

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