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Acta Cryst. (2012). E68, o2711
[ doi:10.1107/S1600536812034940 ]

6,6'-Dimethoxy-2,2'-{[(E,E)-hydrazine-1,2-diylidene]bis(methanylylidene)}diphenol methanol disolvate

N. M. Randell, L. K. Thompson and L. N. Dawe

Abstract: The title compound, C16H16N2O4·2CH3OH, is a hydrazone in an E geometric arrangement, with an inversion centre at the mid-point of the N-N bond. A symmetry-related pair of six-membered hydrogen-bonded rings [graph-set motif S11(6)] are present for the terminal vanillin-imine moieties. Two lattice methanol solvent molecules are present per formula unit (Z' = 1/2), which form hydrogen-bonded chains along [010] with two orientations due to disorder of the methanol H-atom.


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