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Acta Cryst. (2012). E68, m1210-m1211
[ doi:10.1107/S1600536812036410 ]

Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-[kappa]N)phenyl-[kappa]C1]platinum(IV) acetonitrile monosolvate

Y. Wu, D. Xie, D. Zhang, X. Li and W. Jin

Abstract: In the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C-H...Cl hydrogen-bonding interactions and [pi]-[pi] stacking interactions between the tridentate ligands, the shortest ring centroid-centroid distance being 3.613 Å.


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