supplementary materials


hy2575 scheme

Acta Cryst. (2012). E68, m1170    [ doi:10.1107/S1600536812034721 ]

Tetrakis[[mu]-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-[kappa]2N:N']trisilver(I) tris(hexafluoridophosphate)

C.-W. Yeh, Y.-W. Ho, H.-T. Lee, J.-C. Wang and M.-C. Suen

Abstract top

In the title compound, [Ag3(C12H12N2O2)4](PF6)3, one AgI ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetrahedral geometry and the other AgI ion is coordinated by two N atoms from two L ligands in a bent arrangement [N-Ag-N = 169.03 (17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent AgI ions, forming a trinuclear complex. One of the PF6- anions is half-occupied, with the P atom located on a twofold rotation axis. The PF6- anions link the complex molecules via Ag...F interactions [2.80 (2) and 2.85 (2) Å] into a polymeric chain along [100].

Comment top

Several Ag(I), Cd(II) and Cu(II) complexes containing 1,4-bis(4,5-dihydro-2-oxazolyl)benzene ligands have been reported, which show various dimensional structures (Suen et al., 2011; Wang et al., 2008, 2011a,b; Yeh et al., 2011). In the title trinuclear complex, one AgI ion, lying on a twofold axis, is coordinated by four N atoms from four 1,3-bis(4,5-dihydro-2-oxazolyl)benzene (L) ligands in a distorted tetrahedral geometry and the other two are each coordinated by two N atoms from two L ligands in a bent linear arrangement (Fig. 1, Table 1). The Ag···Ag separation in the trimer is 7.473 (1) Å. The L ligands show both syn and anti conformations. The PF6- anions link the trinuclear cationic complexes via Ag···F interactions [2.80 (2) and 2.85 (2) Å], forming one-dimensional beaded polymeric chains along [100] (Fig. 2).

Related literature top

For related structures incorporating the 1,4-bis(4,5-dihydro-2-oxazolyl)benzene ligand, see: Suen et al. (2011); Wang et al. (2008, 2011a,b); Yeh et al. (2011).

Experimental top

An aqueous solution (5.0 ml) of AgPF6 (3.0 mmol) was layered carefully over a methanolic solution (5.0 ml) of 1,3-bis(4,5-dihydro-2-oxazolyl)benzene (4.0 mmol) in a tube and kept it in dark. Colourless crystals were obtained after several weeks. These were washed with methanol and collected in 75.8% yield.

Refinement top

H atoms were positioned geometrically and refined as riding atoms, with C—H = 0.93 (phenyl) and 0.97 (methylene) Å and with Uiso(H) = 1.2Ueq(C).

Computing details top

Data collection: XSCANS (Siemens, 1995); cell refinement: XSCANS (Siemens, 1995); data reduction: XSCANS (Siemens, 1995); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. [Symmetry code: (i) 1-x, y, 1/2-z.]
[Figure 2] Fig. 2. The packing diagram of the title compound, showing the one-dimensional beaded chain formed by Ag···F interactions.
Tetrakis[µ-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene- κ2N:N']trisilver(I) tris(hexafluoridophosphate) top
Crystal data top
[Ag3(C12H12N2O2)4](PF6)3F(000) = 3216
Mr = 1623.46Dx = 1.908 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 36 reflections
a = 22.7473 (16) Åθ = 4.8–12.5°
b = 11.4521 (19) ŵ = 1.23 mm1
c = 24.1382 (15) ÅT = 298 K
β = 116.014 (7)°Plate, colourless
V = 5651.0 (11) Å30.60 × 0.40 × 0.30 mm
Z = 4
Data collection top
Siemens P4 four-circle
diffractometer
3885 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.020
Graphite monochromatorθmax = 25.0°, θmin = 2.0°
ω scansh = 026
Absorption correction: ψ scan
(XSCANS; Siemens, 1995)
k = 013
Tmin = 0.634, Tmax = 0.964l = 2825
5107 measured reflections3 standard reflections every 297 reflections
4976 independent reflections intensity decay: 2.0%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.050Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.137H-atom parameters constrained
S = 1.01 w = 1/[σ2(Fo2) + (0.0628P)2 + 34.3783P]
where P = (Fo2 + 2Fc2)/3
4976 reflections(Δ/σ)max < 0.001
425 parametersΔρmax = 1.02 e Å3
0 restraintsΔρmin = 0.81 e Å3
Crystal data top
[Ag3(C12H12N2O2)4](PF6)3V = 5651.0 (11) Å3
Mr = 1623.46Z = 4
Monoclinic, C2/cMo Kα radiation
a = 22.7473 (16) ŵ = 1.23 mm1
b = 11.4521 (19) ÅT = 298 K
c = 24.1382 (15) Å0.60 × 0.40 × 0.30 mm
β = 116.014 (7)°
Data collection top
Siemens P4 four-circle
diffractometer
3885 reflections with I > 2σ(I)
Absorption correction: ψ scan
(XSCANS; Siemens, 1995)
Rint = 0.020
Tmin = 0.634, Tmax = 0.964θmax = 25.0°
5107 measured reflections3 standard reflections every 297 reflections
4976 independent reflections intensity decay: 2.0%
Refinement top
R[F2 > 2σ(F2)] = 0.050 w = 1/[σ2(Fo2) + (0.0628P)2 + 34.3783P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.137Δρmax = 1.02 e Å3
S = 1.01Δρmin = 0.81 e Å3
4976 reflectionsAbsolute structure: ?
425 parametersFlack parameter: ?
0 restraintsRogers parameter: ?
H-atom parameters constrained
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.50000.06276 (6)0.25000.0564 (2)
Ag20.18074 (2)0.04964 (5)0.26872 (2)0.05790 (18)
O110.31412 (19)0.1417 (4)0.19947 (19)0.0637 (11)
O310.3068 (2)0.0441 (4)0.45572 (19)0.0675 (12)
O410.3592 (2)0.2537 (5)0.08323 (18)0.0694 (13)
O610.14979 (18)0.1693 (4)0.09064 (16)0.0532 (9)
N110.4086 (2)0.0591 (4)0.2133 (2)0.0488 (11)
N310.2312 (2)0.0070 (4)0.3628 (2)0.0507 (11)
N410.4514 (2)0.1949 (5)0.1635 (2)0.0558 (12)
N610.1478 (2)0.1039 (4)0.1765 (2)0.0491 (11)
C110.3711 (2)0.0898 (5)0.2366 (3)0.0458 (12)
C120.3785 (3)0.0977 (6)0.1487 (3)0.0580 (15)
H12A0.40340.16060.14230.070*
H12B0.37530.03370.12120.070*
C130.3111 (3)0.1394 (7)0.1382 (3)0.0712 (19)
H13A0.27740.08600.11160.085*
H13B0.30210.21660.11980.085*
C210.3827 (3)0.0752 (5)0.3012 (3)0.0465 (12)
C220.3315 (3)0.0577 (5)0.3166 (2)0.0457 (12)
H22A0.28880.05560.28560.055*
C230.3426 (3)0.0434 (5)0.3773 (2)0.0469 (12)
C240.4070 (3)0.0470 (6)0.4234 (3)0.0657 (17)
H24A0.41550.03560.46440.079*
C250.4578 (3)0.0674 (6)0.4080 (3)0.0710 (19)
H25A0.50030.07190.43900.085*
C260.4465 (3)0.0810 (6)0.3481 (3)0.0639 (17)
H26A0.48130.09420.33840.077*
C310.2900 (3)0.0254 (5)0.3960 (2)0.0506 (13)
C320.1977 (3)0.0162 (6)0.4034 (3)0.0629 (16)
H32A0.16190.03900.39110.075*
H32B0.18090.09440.40230.075*
C330.2505 (4)0.0123 (8)0.4664 (3)0.080 (2)
H33A0.26030.05490.49360.096*
H33B0.23740.07680.48460.096*
C410.3914 (3)0.2206 (5)0.1427 (2)0.0464 (12)
C420.4700 (3)0.2166 (8)0.1130 (3)0.081 (2)
H42A0.48450.14500.10130.098*
H42B0.50490.27380.12520.098*
C430.4086 (3)0.2623 (8)0.0603 (3)0.080 (2)
H43A0.41420.34260.05080.096*
H43B0.39680.21500.02370.096*
C510.3518 (2)0.2183 (5)0.1772 (2)0.0429 (12)
C520.2861 (2)0.1886 (5)0.1481 (2)0.0430 (12)
H52A0.26630.17090.10620.052*
C530.2499 (2)0.1855 (4)0.1822 (2)0.0407 (11)
C540.2793 (3)0.2170 (5)0.2441 (2)0.0469 (13)
H54A0.25500.21620.26670.056*
C550.3442 (3)0.2492 (5)0.2721 (3)0.0516 (14)
H55A0.36350.27120.31340.062*
C560.3809 (3)0.2492 (5)0.2392 (3)0.0495 (13)
H56A0.42490.26970.25840.059*
C610.1804 (2)0.1498 (5)0.1510 (2)0.0427 (12)
C620.0795 (3)0.0839 (7)0.1278 (3)0.0641 (18)
H62A0.04790.12670.13680.077*
H62B0.06840.00150.12380.077*
C630.0821 (3)0.1300 (6)0.0701 (3)0.0555 (14)
H63A0.07130.06900.03930.067*
H63B0.05180.19430.05270.067*
P10.50000.4236 (2)0.75000.0619 (6)
F10.5316 (14)0.3242 (15)0.7277 (12)0.136 (9)0.50
F20.4658 (10)0.5162 (10)0.7741 (9)0.102 (4)0.50
F30.5624 (8)0.503 (2)0.7726 (12)0.172 (9)0.50
F40.4740 (10)0.490 (2)0.6891 (7)0.151 (6)0.50
F50.5275 (10)0.3615 (19)0.8141 (7)0.135 (5)0.50
F60.4354 (9)0.3566 (19)0.7311 (13)0.156 (8)0.50
P20.12182 (9)0.19994 (18)0.52246 (10)0.0733 (5)
F70.0734 (4)0.1210 (9)0.4738 (4)0.231 (5)
F80.0936 (4)0.2993 (9)0.4800 (5)0.241 (6)
F90.1540 (4)0.1000 (7)0.5635 (6)0.266 (7)
F100.0687 (4)0.2167 (15)0.5419 (5)0.290 (8)
F110.1701 (3)0.2775 (6)0.5752 (3)0.156 (3)
F120.1760 (4)0.1934 (12)0.5037 (4)0.248 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0330 (3)0.0662 (4)0.0635 (4)0.0000.0150 (3)0.000
Ag20.0457 (3)0.0879 (4)0.0438 (3)0.0038 (2)0.0231 (2)0.0128 (2)
O110.045 (2)0.090 (3)0.059 (2)0.027 (2)0.0255 (19)0.016 (2)
O310.082 (3)0.080 (3)0.041 (2)0.009 (2)0.028 (2)0.010 (2)
O410.056 (2)0.114 (4)0.048 (2)0.017 (3)0.031 (2)0.018 (2)
O610.042 (2)0.075 (3)0.042 (2)0.0003 (19)0.0179 (16)0.0088 (19)
N110.035 (2)0.057 (3)0.057 (3)0.008 (2)0.023 (2)0.003 (2)
N310.054 (3)0.059 (3)0.042 (2)0.003 (2)0.024 (2)0.004 (2)
N410.039 (3)0.080 (4)0.056 (3)0.005 (2)0.029 (2)0.011 (2)
N610.035 (2)0.074 (3)0.043 (2)0.004 (2)0.0216 (19)0.007 (2)
C110.036 (3)0.043 (3)0.056 (3)0.000 (2)0.017 (2)0.000 (2)
C120.048 (3)0.067 (4)0.063 (4)0.009 (3)0.029 (3)0.009 (3)
C130.063 (4)0.096 (5)0.057 (4)0.026 (4)0.029 (3)0.019 (4)
C210.039 (3)0.046 (3)0.053 (3)0.006 (2)0.018 (2)0.001 (2)
C220.040 (3)0.045 (3)0.044 (3)0.003 (2)0.011 (2)0.003 (2)
C230.043 (3)0.046 (3)0.045 (3)0.003 (2)0.013 (2)0.005 (2)
C240.066 (4)0.074 (4)0.041 (3)0.009 (3)0.008 (3)0.005 (3)
C250.045 (3)0.087 (5)0.059 (4)0.003 (3)0.001 (3)0.011 (3)
C260.037 (3)0.075 (4)0.069 (4)0.003 (3)0.014 (3)0.008 (3)
C310.065 (4)0.047 (3)0.038 (3)0.005 (3)0.021 (3)0.002 (2)
C320.076 (4)0.064 (4)0.064 (4)0.001 (3)0.045 (3)0.005 (3)
C330.087 (5)0.112 (6)0.050 (4)0.007 (5)0.039 (4)0.001 (4)
C410.047 (3)0.051 (3)0.046 (3)0.000 (2)0.024 (2)0.001 (2)
C420.065 (4)0.126 (7)0.074 (4)0.016 (4)0.050 (4)0.027 (4)
C430.069 (4)0.128 (7)0.061 (4)0.005 (4)0.046 (4)0.011 (4)
C510.039 (3)0.048 (3)0.045 (3)0.007 (2)0.021 (2)0.005 (2)
C520.042 (3)0.050 (3)0.041 (3)0.006 (2)0.021 (2)0.004 (2)
C530.035 (3)0.045 (3)0.044 (3)0.007 (2)0.019 (2)0.004 (2)
C540.045 (3)0.059 (3)0.045 (3)0.010 (3)0.027 (2)0.005 (2)
C550.049 (3)0.065 (4)0.044 (3)0.001 (3)0.023 (3)0.006 (3)
C560.039 (3)0.060 (4)0.050 (3)0.003 (3)0.020 (2)0.000 (3)
C610.040 (3)0.047 (3)0.043 (3)0.008 (2)0.021 (2)0.004 (2)
C620.035 (3)0.109 (5)0.047 (3)0.011 (3)0.017 (2)0.005 (3)
C630.041 (3)0.071 (4)0.049 (3)0.004 (3)0.015 (2)0.006 (3)
P10.0493 (12)0.0745 (16)0.0784 (16)0.0000.0431 (12)0.000
F10.21 (3)0.091 (9)0.20 (2)0.038 (14)0.18 (2)0.011 (13)
F20.124 (13)0.075 (6)0.157 (12)0.029 (8)0.108 (11)0.014 (8)
F30.071 (9)0.21 (2)0.23 (2)0.047 (10)0.064 (13)0.034 (19)
F40.142 (13)0.225 (18)0.118 (11)0.074 (14)0.086 (11)0.076 (12)
F50.157 (13)0.161 (15)0.105 (9)0.074 (12)0.074 (9)0.066 (10)
F60.101 (11)0.142 (19)0.25 (3)0.054 (11)0.101 (15)0.039 (16)
P20.0472 (9)0.0794 (13)0.0804 (12)0.0067 (9)0.0161 (9)0.0022 (10)
F70.147 (7)0.200 (9)0.208 (9)0.008 (6)0.048 (6)0.083 (7)
F80.140 (6)0.246 (11)0.283 (12)0.054 (7)0.043 (7)0.168 (10)
F90.118 (6)0.153 (7)0.368 (14)0.043 (5)0.041 (7)0.137 (8)
F100.091 (5)0.61 (2)0.194 (8)0.005 (9)0.086 (6)0.080 (12)
F110.110 (5)0.137 (5)0.166 (6)0.005 (4)0.010 (4)0.052 (5)
F120.139 (6)0.457 (18)0.165 (7)0.096 (9)0.082 (6)0.042 (9)
Geometric parameters (Å, º) top
Ag1—N112.331 (4)C32—H32A0.9700
Ag1—N412.418 (5)C32—H32B0.9700
Ag2—N312.104 (5)C33—H33A0.9700
Ag2—N612.106 (4)C33—H33B0.9700
O11—C111.348 (6)C41—C511.472 (7)
O11—C131.450 (7)C42—C431.511 (10)
O31—C311.335 (7)C42—H42A0.9700
O31—C331.460 (8)C42—H42B0.9700
O41—C411.348 (7)C43—H43A0.9700
O41—C431.457 (7)C43—H43B0.9700
O61—C611.329 (6)C51—C521.387 (7)
O61—C631.467 (7)C51—C561.391 (7)
N11—C111.260 (7)C52—C531.396 (7)
N11—C121.469 (7)C52—H52A0.9300
N31—C311.276 (8)C53—C541.391 (7)
N31—C321.485 (7)C53—C611.479 (7)
N41—C411.264 (7)C54—C551.378 (8)
N41—C421.478 (7)C54—H54A0.9300
N61—C611.269 (7)C55—C561.382 (7)
N61—C621.498 (7)C55—H55A0.9300
C11—C211.474 (8)C56—H56A0.9300
C12—C131.517 (8)C62—C631.515 (8)
C12—H12A0.9700C62—H62A0.9700
C12—H12B0.9700C62—H62B0.9700
C13—H13A0.9700C63—H63A0.9700
C13—H13B0.9700C63—H63B0.9700
C21—C221.384 (8)P1—F41.527 (12)
C21—C261.396 (8)P1—F61.539 (16)
C22—C231.383 (8)P1—F11.562 (13)
C22—H22A0.9300P1—F51.564 (11)
C23—C241.398 (8)P1—F31.566 (16)
C23—C311.469 (8)P1—F21.570 (11)
C24—C251.380 (10)P2—F81.476 (8)
C24—H24A0.9300P2—F91.481 (7)
C25—C261.363 (10)P2—F121.488 (8)
C25—H25A0.9300P2—F101.490 (7)
C26—H26A0.9300P2—F71.509 (7)
C32—C331.504 (10)P2—F111.546 (6)
N11—Ag1—N11i106.5 (2)O61—C63—C62104.7 (4)
N11—Ag1—N41i134.17 (16)O61—C63—H63A110.8
N11i—Ag1—N41i93.01 (17)C62—C63—H63A110.8
N11—Ag1—N4193.01 (17)O61—C63—H63B110.8
N11i—Ag1—N41134.17 (16)C62—C63—H63B110.8
N41i—Ag1—N41102.5 (3)H63A—C63—H63B108.9
N31—Ag2—N61169.03 (17)F4ii—P1—F4120 (2)
C11—O11—C13105.7 (4)F4ii—P1—F6116.9 (11)
C31—O31—C33107.0 (5)F4—P1—F692.7 (16)
C41—O41—C43105.9 (5)F4ii—P1—F6ii92.7 (16)
C61—O61—C63106.7 (4)F4—P1—F6ii116.9 (11)
C11—N11—C12107.2 (4)F6—P1—F6ii120.2 (18)
C11—N11—Ag1131.5 (4)F4ii—P1—F1ii94.4 (10)
C12—N11—Ag1120.5 (3)F6ii—P1—F1ii93.3 (12)
C31—N31—C32107.7 (5)F4ii—P1—F1130.8 (17)
C31—N31—Ag2132.2 (4)F4—P1—F194.4 (10)
C32—N31—Ag2120.1 (4)F6—P1—F193.3 (12)
C41—N41—C42106.4 (5)F1ii—P1—F186.4 (13)
C41—N41—Ag1119.6 (4)F4ii—P1—F5ii177.0 (16)
C42—N41—Ag1129.0 (4)F4—P1—F5ii57.1 (9)
C61—N61—C62107.9 (4)F6—P1—F5ii64.2 (9)
C61—N61—Ag2128.5 (4)F6ii—P1—F5ii89.0 (10)
C62—N61—Ag2123.4 (3)F1ii—P1—F5ii88.0 (11)
N11—C11—O11118.0 (5)F1—P1—F5ii51.1 (9)
N11—C11—C21126.8 (5)F4ii—P1—F557.1 (9)
O11—C11—C21115.2 (5)F4—P1—F5177.0 (17)
N11—C12—C13103.9 (5)F6—P1—F589.0 (10)
N11—C12—H12A111.0F6ii—P1—F564.2 (9)
C13—C12—H12A111.0F1ii—P1—F551.1 (9)
N11—C12—H12B111.0F1—P1—F588.0 (11)
C13—C12—H12B111.0F5ii—P1—F5125.9 (18)
H12A—C12—H12B109.0F4ii—P1—F357.7 (9)
O11—C13—C12104.0 (5)F4—P1—F387.4 (11)
O11—C13—H13A111.0F6—P1—F3173.3 (12)
C12—C13—H13A111.0F6ii—P1—F365.4 (11)
O11—C13—H13B111.0F1ii—P1—F3141.7 (17)
C12—C13—H13B111.0F1—P1—F393.3 (12)
H13A—C13—H13B109.0F5ii—P1—F3121.0 (10)
C22—C21—C26119.2 (6)F5—P1—F390.6 (16)
C22—C21—C11121.3 (5)F4ii—P1—F3ii87.4 (11)
C26—C21—C11119.5 (5)F4—P1—F3ii57.7 (9)
C23—C22—C21121.1 (5)F6—P1—F3ii65.4 (11)
C23—C22—H22A119.4F6ii—P1—F3ii173.3 (12)
C21—C22—H22A119.4F1ii—P1—F3ii93.3 (12)
C22—C23—C24118.8 (6)F1—P1—F3ii141.7 (17)
C22—C23—C31123.2 (5)F5ii—P1—F3ii90.6 (16)
C24—C23—C31118.0 (5)F5—P1—F3ii121.0 (10)
C25—C24—C23119.9 (6)F3—P1—F3ii109.4 (18)
C25—C24—H24A120.0F4ii—P1—F249.6 (8)
C23—C24—H24A120.0F4—P1—F288.4 (9)
C26—C25—C24121.0 (6)F6—P1—F283.2 (11)
C26—C25—H25A119.5F6ii—P1—F2142.3 (15)
C24—C25—H25A119.5F1ii—P1—F289.3 (8)
C25—C26—C21119.9 (6)F1—P1—F2175.7 (8)
C25—C26—H26A120.0F5ii—P1—F2128.7 (14)
C21—C26—H26A120.0F5—P1—F289.3 (8)
N31—C31—O31116.8 (5)F3—P1—F290.1 (9)
N31—C31—C23128.2 (5)F4ii—P1—F2ii88.4 (9)
O31—C31—C23115.0 (5)F4—P1—F2ii49.6 (8)
N31—C32—C33103.9 (5)F6—P1—F2ii142.3 (15)
N31—C32—H32A111.0F6ii—P1—F2ii83.2 (11)
C33—C32—H32A111.0F1ii—P1—F2ii175.7 (8)
N31—C32—H32B111.0F1—P1—F2ii89.3 (8)
C33—C32—H32B111.0F5ii—P1—F2ii89.3 (8)
H32A—C32—H32B109.0F5—P1—F2ii128.7 (14)
O31—C33—C32104.3 (5)F3ii—P1—F2ii90.1 (9)
O31—C33—H33A110.9F2—P1—F2ii95.1 (9)
C32—C33—H33A110.9F6ii—F1—F5ii133 (2)
O31—C33—H33B110.9F6ii—F1—P169.6 (14)
C32—C33—H33B110.9F5ii—F1—P164.5 (9)
H33A—C33—H33B108.9F3ii—F2—F4ii132.4 (16)
N41—C41—O41118.5 (5)F3ii—F2—P170.6 (13)
N41—C41—C51126.3 (5)F4ii—F2—P163.5 (8)
O41—C41—C51115.2 (5)F2ii—F3—F4ii116.2 (18)
N41—C42—C43105.0 (5)F2ii—F3—P170.9 (11)
N41—C42—H42A110.8F4ii—F3—P159.8 (8)
C43—C42—H42A110.8F2ii—F3—F6ii96 (2)
N41—C42—H42B110.8F4ii—F3—F6ii89 (2)
C43—C42—H42B110.8P1—F3—F6ii56.5 (9)
H42A—C42—H42B108.8F2ii—F4—F5ii104.8 (12)
O41—C43—C42103.9 (5)F2ii—F4—F3ii105.1 (17)
O41—C43—H43A111.0F5ii—F4—F3ii97.0 (18)
C42—C43—H43A111.0F2ii—F4—P166.9 (8)
O41—C43—H43B111.0F5ii—F4—P162.7 (7)
C42—C43—H43B111.0F3ii—F4—P162.5 (8)
H43A—C43—H43B109.0F1ii—F5—F4ii106.5 (13)
C52—C51—C56120.5 (5)F1ii—F5—P164.4 (8)
C52—C51—C41120.6 (5)F4ii—F5—P160.2 (7)
C56—C51—C41118.9 (5)F1ii—F5—F6ii97.1 (15)
C51—C52—C53119.3 (5)F4ii—F5—F6ii90.2 (15)
C51—C52—H52A120.3P1—F5—F6ii57.2 (7)
C53—C52—H52A120.3F1ii—F6—P172.1 (15)
C54—C53—C52119.8 (5)F1ii—F6—F5ii107 (2)
C54—C53—C61121.4 (4)P1—F6—F5ii58.6 (7)
C52—C53—C61118.8 (5)F1ii—F6—F3ii113 (3)
C55—C54—C53120.3 (5)P1—F6—F3ii58.1 (8)
C55—C54—H54A119.9F5ii—F6—F3ii84.0 (17)
C53—C54—H54A119.9F8—P2—F9175.8 (7)
C54—C55—C56120.3 (5)F8—P2—F1289.7 (6)
C54—C55—H55A119.8F9—P2—F1286.1 (7)
C56—C55—H55A119.8F8—P2—F1087.3 (7)
C55—C56—C51119.7 (5)F9—P2—F1096.8 (8)
C55—C56—H56A120.1F12—P2—F10175.4 (9)
C51—C56—H56A120.1F8—P2—F788.6 (6)
N61—C61—O61117.7 (5)F9—P2—F792.0 (6)
N61—C61—C53126.2 (5)F12—P2—F798.8 (6)
O61—C61—C53116.1 (4)F10—P2—F784.6 (6)
N61—C62—C63103.0 (4)F8—P2—F1193.7 (6)
N61—C62—H62A111.2F9—P2—F1185.9 (5)
C63—C62—H62A111.2F12—P2—F1184.0 (5)
N61—C62—H62B111.2F10—P2—F1192.8 (6)
C63—C62—H62B111.2F7—P2—F11176.4 (6)
H62A—C62—H62B109.1
Symmetry codes: (i) x+1, y, z+1/2; (ii) x+1, y, z+3/2.
Selected bond lengths (Å) top
Ag1—N112.331 (4)Ag2—N312.104 (5)
Ag1—N412.418 (5)Ag2—N612.106 (4)
Acknowledgements top

We are grateful to the National Science Council of the Republic of China and the Taoyuan Innovation Institute of Technology for support.

references
References top

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Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.

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Suen, M.-C., Yeh, C.-W., Lin, S.-C. & Hsu, Y.-F. (2011). Acta Cryst. E67, m1099.

Wang, Y.-H., Lee, H.-T. & Suen, M.-C. (2008). Polyhedron, 27, 1177–1184.

Wang, P.-N., Yeh, C.-W., Lee, H.-T. & Suen, M.-C. (2011a). Acta Cryst. E67, m1083.

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Yeh, C.-W., Huang, F.-C., Jong, A. & Suen, M.-C. (2011). Acta Cryst. E67, m1080–m1081.