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Acta Cryst. (2012). E68, m1222-m1223
[ doi:10.1107/S1600536812036318 ]

catena-Poly[[[diaqua(1,10-phenanthroline-[kappa]2N,N')zinc]-[mu]-4,4'-bipyridine-[kappa]2N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate]

S. Xu, Y.-C. Dai, Q.-M. Qiu, Q.-H. Jin and C.-L. Zhang

Abstract: In the title compound, [Zn(C10H8N2)(C12H8N2)(H2O)2](NO3)2·0.5C10H8N2·H2O, the ZnII atom is coordinated in a distorted octahedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water molecules. The 4,4'-bipy ligands bridge the ZnII atoms into a chain structure along [100]. The uncoordinated 4,4'-bipy molecule lies on an inversion center. O-H...O and O-H...N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,4'-bipy molecules and the water molecules into tow-dimensional networks.


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