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Acta Cryst. (2012). E68, m1226-m1227
[ doi:10.1107/S1600536812036677 ]

Hexakis{[1-(dimethylamino)propylidene]oxidanium} bis(dodecamolybdophosphate) N,N-dimethylpropionamide pentasolvate

A. Raissi Shabari, M. Pourayoubi and S. Derakhshan Rad

Abstract: In the asymmetric unit of the title salt, (C5H12NO)6[PMo12O40]2·5C5H11NO, there are two independent [alpha]-Keggin-type [PMo12O40]3- polyoxidoanions, which show characteristic features with respect to bond lengths and angles. One of the [CH3CH2C(=OH)N(CH3)2]+ cations is hydrogen bonded to the neighboring polyoxidoanion through a C=O-H...Obridge hydrogen bond. The organic molecules and the remaining organic cations form [(C5H11NO)2H]+ molecule-cation pairs, two of which lie about inversion centers, through O-H...O hydrogen bonds.


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