Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)


metal-organic compounds



lh5512 scheme

Acta Cryst. (2012). E68, m1178    [ doi:10.1107/S1600536812035246 ]

Poly[[diaquabis[[mu]-2-(4-fluorophenoxy)acetato-[kappa]2O1:O1']magnesium] 0.4-hydrate]

G. Smith

Abstract: In the title compound, {[Mg(C8H6FO3)2(H2O)2]·0.4H2O}n, slightly distorted octahedral MgO6 complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within the two-dimensional complex polymer which is parallel to (100), coordinating water molecules form intermolecular O-H...O hydrogen bonds with carboxylate and phenoxy O-atom acceptors, as well as with the partial-occupancy solvent water molecules.


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