Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)

metal-organic compounds

 

Poly[[diaquabis[-2-(4-fluorophenoxy)acetato-²O¹:O^1']magnesium] 0.4-hydrate]

G. Smith

Abstract: In the title compound, {[Mg(C₈H₆FO₃)₂(H₂O)₂]·0.4H₂O}_n, slightly distorted octahedral MgO₆ complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within the two-dimensional complex polymer which is parallel to (100), coordinating water molecules form intermolecular O-HO hydrogen bonds with carboxylate and phenoxy O-atom acceptors, as well as with the partial-occupancy solvent water molecules.

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