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Acta Cryst. (2012). E68, m1164
[ doi:10.1107/S1600536812033454 ]

[[mu]-(3,4,5,6,7-[eta]:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetramethyl-2,8-disilatricyclo[7.3.0.03,7]dodecatetraenediyl]bis[dicarbonylruthenium(I)]

B. Zhu

Abstract: The title compound, [Ru2(C22H34Si2)(CO)4], contains two RuI atoms linked by a bridging ([eta]5-tBuC5H2)2(SiMe2)2 ligand (tBu is a tert-butyl and Me is a methyl group) with an Ru-Ru bond length of 2.8401 (7) Å. The dihedral angle between the planes of the cyclopentadienyl rings of the ligand is 123.13 (19)°. The four terminal carbonyl ligands are bound in a symmetrical and staggered array. In the crystal, molecules are linked via pairs of C-H...O hydrogen bonds, forming inversion dimers.


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