Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)

metal-organic compounds

vn2046 scheme

Acta Cryst. (2012). E68, m1201 [ doi:10.1107/S1600536812035957 ]

fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-²O,P]rhenium(I)

C. Apostolidis, M. Ahlmann and O. Walter

Abstract: The structure of the title complex, [ReBr(C₁₃H₁₉OP)(CO)₃], displays a facial coordination of the three CO ligands and a [kappa] ²O,P coordination mode of the 2-diisopropylphosphinobenzaldehyde ligands. The Re-C bond distance for the CO ligand trans to the P atom is, due to its trans influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two.


	Hyper-Text Markup Language (HTML) file [ doi:10.1107/S1600536812035957/vn2046sup0.html ] Supplementary materials

	MDL mol file (1.8 kbytes) [ doi:10.1107/S1600536812035957/vn2046Isup3.mol ] Supplementary material

Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

Search: From to Advanced search