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Acta Cryst. (2012). E68, o2625
[ doi:10.1107/S1600536812033727 ]

1-[4-(4-Fluorophenyl)-6-methyl-2-sulfanylidene-1,2,3,4-tetrahydropyrimidin-5-yl]ethanone

N. Anuradha, A. Thiruvalluvar, S. Chitra, D. Devanathan and R. J. Butcher

Abstract: In the title molecule, C13H13FN2OS, the heterocyclic ring adopts a slightly distorted flattened boat conformation, and the plane through the four coplanar atoms makes a dihedral angle of 87.45 (14)° with the benzene ring. The thione, acetyl and methyl groups lie on the opposite side of the heterocyclic mean plane to the fluorophenyl group, which has an axial orientation. N-H...O, N-H...S, C-H...F and C-H...O intermolecular hydrogen bonds and a weak C-H...[pi] interaction involving the benzene ring are found in the crystal structure.


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