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Acta Cryst. (2012). E68, m1196-m1197
[ doi:10.1107/S1600536812035647 ]

Poly[([mu]5-2,2'-bipyridine-5,5'-dicarboxylato)lead(II)]

M. Sertçelik, N. Çaylak Delibas, S. Çevik, H. Necefoglu and T. Hökelek

Abstract: In the title polymeric compound, [Pb(C12H6N2O4)]n, the PbII cation, located on a mirror plane, is N,N'-chelated by a 2-2'-bipyridine-5,5'-dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N2O6 geometry. The carboxylate groups bridge the PbII cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.


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