Acta Cryst. (2012). E68, o2704
[ doi:10.1107/S1600536812035301 ]

N-(2,4-Dichlorophenyl)-1,3-thiazol-2-amine

A. Babar, M. A. Munawar, M. N. Tahir, F. Ullah and M. I. Tariq

Abstract: In the title molecule, C₉H₆Cl₂N₂S, the mean planes of the benzene and thiazole rings make a dihedral angle of 54.18 (8)°. In the crystal, molecules are joined into dimers with an R₂²(8) ring motif by pairs of N-HN hydrogen bonds. These dimers are linked by C-HCl interactions into layers parallel to (011). The thiazole rings form columns along the c-axis direction, with a centroid-centroid separation of 3.8581 (9) Å, indicating - interactions. An intramolecular C-HS contact also occurs.

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